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1. | EXECUTIVE SUMMARY AND CONCLUSIONS |
1.1. | Conductive inks and paste: everything is changing and the rising tide of PV |
1.1. | Ten-year market forecasts in USD for all conductive inks and pastes split by 24 application areas |
1.2. | Ten-year market forecasts in USD for all conductive inks and pastes split by application. PV excluded. |
1.2. | Traditional Markets |
1.2.1. | Photovoltaics |
1.2.2. | Touch screen market |
1.2.3. | Automotive |
1.2.4. | Sensors |
1.3. | RFID |
1.3. | Ten-year market forecasts in tonnes for all conductive inks and pastes split by application. PV included. |
1.4. | Ten-year market forecasts in tonnes for all conductive inks and pastes split by application. PV excluded. |
1.4. | Emerging applications |
1.4.1. | 3D antennas |
1.4.2. | ITO replacement |
1.4.3. | Stretchable inks |
1.4.4. | Desktop PCB printing |
1.4.5. | 3D Printed Electronics |
1.5. | Ten-year market forecast for micron-sized (non nano) conductive inks and pastes split by application |
1.6. | Ten-year market forecasts for silver nanoparticle conductive inks and pastes split by application |
1.7. | Ten-year market forecasts for conductive inks and pastes in touch screens |
1.8. | Ten-year market forecasts for conductive inks and pastes in the automotive sector as de-foggers, seat heaters and occupancy sensors. |
1.9. | Ten-year market forecasts for conductive inks and pastes as piezoresistive sensors in value and tonnes |
1.10. | Conductive inks and pastes used in capacitive (non-transparent) touch in value and tonnes |
1.11. | Conductive inks and pastes used in glucose test strips in value and tonne (carbon excluded) |
1.12. | Conductive inks and pastes used in printing UHF RFID antennas in value and tonne |
1.13. | Conductive inks and pastes used in printing HF RFID antennas in value and tonnes |
1.14. | Ten-year market forecasts for conductive inks and pastes in 3D antennas |
1.15. | Ten-year market forecasts for IME conductive inks and pastes in the automotive sector |
1.16. | Ten-year market forecasts for IME conductive inks and pastes in white good appliances |
1.17. | Ten-year market forecasts for conductive inks and pastes in ITO replacement |
1.18. | Ten-year market forecasts for stretchable conductive inks and pastes in e-textiles |
1.19. | Market for conductive inks in desktop and professional PCB printing |
1.20. | Ten-year market forecasts for stretchable conductive inks and pastes in 3D printed electronics. |
2. | CONDUCTIVE INKS AND PASTES |
2.1. | PTF vs Firing Paste |
2.1. | These tables show the performance and processing conditions of screen-printable silver pastes. |
2.1. | Different morphologies of micron-sized silver particulates used in conductive paste/ink making |
2.2. | The process flow for making a conductive pastes. |
2.2. | Table listing the key suppliers of metallic powders/flakes and conductive inks/paste. |
2.2. | Curing and sintering |
2.3. | Value chain |
2.3. | Performance and typical characteristics of various silver nanoparticle inks on the market. |
2.3. | These charts show the curing behaviour of PTFTs using a box oven and UV heater. |
2.4. | These charts show a typical firing profile for firing-type conductive pastes |
2.4. | List of silver nanoparticle suppliers. |
2.4. | Silver nanoparticle inks |
2.5. | Silver nanoparticle inks are more conducting |
2.5. | Typical equipment used in curing silver PTFs |
2.6. | A roll-to-roll photosintering machine by Novacentrix |
2.6. | Curing temperature of silver nanoparticle inks |
2.6.1. | Enhanced Flexibility |
2.6.2. | Inkjet Printability |
2.7. | Price competiveness of silver nanoparticles |
2.7. | A Xenon photosetting machine as well as its lamp |
2.8. | SEM images of flake and spherical Ag pastes after heat and photo curing. |
2.8. | Performance of silver nanoparticle |
2.9. | Value chain |
2.9. | Images comparing the packing of flake-based and nanoparticle-based conductive lines. |
2.10. | Conductivity values of different sputtered and printed conductive materials. |
2.11. | This measured data shows that silver nanoparticle inks can form lines that are both thinner and more conducting. |
2.12. | Melting temperature as a function of gold particle size |
2.13. | Current and projected roadmap for the curing temperature and resistivity level of silver nanoparticle inks. |
2.14. | Data showing the thermal curing behaviour of silver nanoparticle inks. It is observed that silver nanoparticle inks require curing temperatures comparable to PTF pastes. |
3. | SILVER NANOPARTICLE PRODUCTION METHODS |
4. | COPPER INKS AND PASTE |
4.1. | Methods of preventing copper oxidisation |
4.1. | List of companies supplying or researching copper or silver alloy powders, inks or pastes. |
4.1. | Spot price of silver as a function of year |
4.1.1. | Superheated steam |
4.1.2. | Reactive agent metallization |
4.1.3. | Photocuring and photosintering |
4.2. | The performance and key characteristics of copper inks and pastes offered by different companies |
4.2. | Pricing strategy and performance of copper inks and pastes |
4.2. | The annealing method is a key step in creating conductive tracks from copper. |
4.3. | Apparatus and process for curing printed copper lines using Toyobo's superheated steam. |
4.3. | Copper oxide nanoparticles |
4.4. | Silver-Coated Copper |
4.4. | Creative copper conductive traces using reactive agent metallization |
4.5. | Various photosintering machines |
4.6. | Comparing an ideal silver-coated copper vs the ones typically produced. |
5. | CONDUCTIVE PASTES IN THE PHOTOVOLTAIC MARKET |
5.1. | Background to the PV industry |
5.1. | Left: price history of silicon PV cells. Right: price levels and production volumes of crystalline silicon PV. The price levels are now around 30 cents per watt or less. |
5.2. | Price learning curve of c-Si and thin film PV technologies |
5.2. | The return of the boom and bust to the PV sector? |
5.3. | Massive Chinese investments buoys the market |
5.3. | The large-scale loans made available to Chinese producers between 2010 and 2012, establishing the financial basis for the expansion of production capacity. |
5.4. | List of companies that went bankrupt, closed, restructured or sold equity at discount prices during the consolidation period. |
5.4. | China takes markets to new heights but will the change in FiTs finally cool it down? |
5.5. | Conductive pastes in the PV sectors |
5.5. | Shipped production for the top 10 suppliers of solar cells. |
5.6. | The industry has dramatically changed over the years. US Japan and Europe have lost their leading positions at various times whereas Japan has risen. |
5.6. | Alternative and improved metallization techniques |
5.7. | Silicon inks |
5.7. | Production in GW of solar energy by China-Taiwan, Japan, Europe, North America and Row between 2005 and 2017 |
5.8. | Comparing production volumes, measured in megawatts, of different solar cells technologies in 2013(red bars) and 2014 (blue bars). |
5.8. | Copper metallization in solar cells |
5.9. | Trends and changes in solar cell architecture |
5.9. | Market share of different PV technologies: Si (wafer-based), a-Si, Cd-Te and CIGS |
5.10. | Cost breakdown of a typical wafer-based silicon solar cells. |
5.10. | Market dynamics |
5.11. | Ten-year market forecasts for conductive paste in solar cells |
5.11. | The cost of silver conductive paste as an overall portion of the energy-generation cost of a silicon PV (in cents per watt peak) as a function of time. |
5.12. | Annual GW PV installation by year by region between 2005 to 2020 |
5.12. | Silver nanoparticles are finally adopted in the thin film photovoltaic business? |
5.13. | Stock price of largest PV manufacturers worldwide |
5.14. | Table outlining the changes in China's Feed-in-Tariffs between 2016 and 2017 for different regions in RMB/kWh. |
5.15. | Photovoltaic market forecasts |
5.16. | Screen printed conductive lines on a typical wafer-based silicon PV. |
5.17. | The production process for a silicon PV showing when metallization and curing (firing) takes place |
5.18. | Typical curing profile of firing-type conductive pastes used in the photovoltaic industry. |
5.19. | Silver content per cell as a function of time. These are IDTechEx projections and underpin our market forecasts. We are more conservative that industry projections on how much silver consumption per cell can be reduced. The techno |
5.20. | Projections reductions in silver consumption per wafer by ITRPV over the years. The projections are for years 2011, 2013, 2014, 2015 and 2016. It demonstrates the difficulty in predicting future silver consumption per wafer even |
5.21. | The reduction in the silver content is made by possible by innovation in inks. |
5.22. | Survey results showing what the industry expected in the next decade |
5.23. | Predicted trend for minimum as-cut wafer thickness |
5.24. | Benefits of a silicon ink in improving solar cell efficiency |
5.25. | Methods of plating the metallization layers: (1) thickening a screen printed Ag line with; (2) direct plating on Si. |
5.26. | Current efficiency of select commercial PV modules. |
5.27. | Market share of different silicon solar cell architectures/technologies |
5.28. | Comparing the BSF and PERC cell architecture |
5.29. | 2018-2028 market forecasts for conductive pastes in wafer-based Si photovoltaic in tons and value. |
5.30. | Describing the basics and production process behind CIGS technology. |
6. | AUTOMOTIVE |
6.1. | De-misters or de-foggers |
6.1. | Existing and emerging use cases of conductive inks in the interior and exterior of cars |
6.2. | Comparing the performance of a standard conductive paste as a de-froster when deposited on a PC and a glass substrate. |
6.2. | Laser transfer printing as a new process? |
6.3. | Transparent conductors as replacement for printed heaters? |
6.3. | Ten-year market forecast for conductive paste used in de-foggers |
6.4. | Laser transfer printing process |
6.4. | Car seat heaters |
6.5. | Seat sensors |
6.5. | Structure of a typical printed seat heater |
6.6. | PTC carbon inks with Ag bus bars to form a heater. |
6.6. | High power electronics represent a major growth opportunity |
6.7. | Resistance vs temperature behaviour of a PTF carbon ink |
6.8. | Ten-year market forecasts for the use of conductive inks (carbon plus silver) in car seat heaters |
6.9. | Operation of a FSR |
6.10. | Response curve of a typical FSR from IEE. Product name: CP 149 Sensor |
6.11. | Examples of FSR individual sensors from IEE |
6.12. | Ten-year market forecasts for the use of conductive inks and pastes as occupancy sensors in cars. |
7. | 3D PRINTED ELECTRONICS |
7.1. | Progress in 3D printed electronics |
7.1. | Ten-year market projections for 3D printing industrial machines split by SLA/DLP, extrusion, metal powder, binder jetting, etc. in annual unit sales. |
7.1.1. | Nascent Objects (now Facebook) |
7.1.2. | Voxel8 |
7.1.3. | nScrypt ad Novacentrix |
7.2. | University of Texas at El Paso (UTEP) |
7.2. | Ten-year market projections for 3D printing personal machines (desktop machines) in annual unit sales |
7.3. | Plastic filaments used in 3D printing and suppliers thereof |
7.3. | Nagase |
7.4. | Ten-year market projections for conductive inks and pastes in 3D printed electronics |
7.4. | Plastic powders used in 3D printing and suppliers thereof |
7.5. | Examples of embedded and metallized 3D printed objects. |
7.6. | Nascent Objects seeks to modularize electronic components so that they can placed inside 3D printed objects and upgraded (exchanged) when new versions arrive |
7.7. | A Voxel8 3D printed electronics machine |
7.8. | A 3D printed electronics object with embedded circuitry |
7.9. | A 3D printed quadcopter with 3D printed embedded circuit |
7.10. | (Left) Photonically-cured copper in and (right) nScrypt's patented SmartPump |
7.11. | nScrypt 3D printed electronic equipment. This is a highly stable hybrid 3DP extruder with a paste dispenser together with photonic curing for the conductive traces. The sales price is around $0.5m per machine. I took this photo at |
7.12. | 3D printed electronics objects by University of Texas |
7.13. | Performance sheet for Nagase Ag nano ink compatible with multiple plastic substrates and suitable for the 3DPE market. |
7.14. | IDTechEx market forecasts for conductive inks and pastes in 3D printed electronics (in tons and value) |
8. | TOUCH PANEL EDGE ELECTRODES |
8.1. | Narrow bezels change the market |
8.1. | Schematic of a touch screen system and a close-up of printed edge electrodes |
8.2. | The process flow for patterning photo-patterned Ag conductive pastes by Toray (Raybrid) |
8.2. | Laser cut vs photopatternable inks |
8.3. | Ten-year market projections for conductive inks and paste in the touch screen industry |
8.3. | Table showing the linewidth resolution of various processes used in making touch screen bezels |
8.4. | Ten-year market forecasts for conductive inks and pastes in value split by touch screen device type |
8.5. | Ten-year market forecasts for conductive inks and pastes in tonne split by touch screen device type |
9. | CONDUCTIVE INKS IN RFID |
9.1. | RFID market size and business dynamics |
9.1. | Table outlining the operational frequency and main features of each RFID tag. |
9.1. | Examples of RFID tags |
9.2. | Typical examples of RFID antennas |
9.2. | Average sales price of passive RFID tags in USD cents |
9.2. | Processes, Material Options and Market Shares |
9.3. | Transparent ultra low-resistivity RF antenna using printed metal mesh technology |
9.3. | The approximate cost breakdown of different components in a typical UHF RFID tag |
9.4. | RFID tag figures and ten-year forecasts by application in billion USD |
9.4. | Ten-year market projections for conductive inks in UHF and HF RFID antennas |
9.5. | Cost estimates for making RFID antennas using different production processes |
9.6. | A Suica transit card widely used in Japan's transport network. The antenna consist of a printed silver conductive track |
9.7. | Comparing the printing speed, thickness and applications of different printing techniques |
9.8. | Schematics of different printing processes used in RFID antenna production |
9.9. | Examples of printed RFID antennas. |
9.10. | Examples of printed transparent antenna using printed metal mesh technology |
9.11. | Ten year market forecast for the use of conductive inks in UHF RFID antennas split by ink type (Cu, Ag (micron), and Ag(nano)). |
9.12. | Ten year market forecast for the use of conductive inks in HF RFID antennas split by ink type (Cu, Ag (micron), and Ag(nano)). |
10. | PRINTED AND FLEXIBLE SENSORS |
10.1. | Piezoresistive |
10.1. | Typical construction and behaviour of piezoresistive force sensors. |
10.2. | The IDTechEx market and technology roadmap for piezoresistive sensors |
10.2. | Glucose sensors |
10.3. | Market forecasts for conductive inks in glucose test strips |
10.3. | Ten-year market projections for piezoresistive sensors at the device level |
10.4. | Ten-year market forecasts for conductive inks/pastes in printed piezoresistive sensors by value and tonnes |
10.4. | Capacitive sensors |
10.5. | Different glucose test strips on the market. |
10.6. | The anatomy of a glucose test strip. The working electrode here is carbon based |
10.7. | Manufacturing steps of a Lifescan Ultra glucose test strip. |
10.8. | Benchmarking printing vs. sputtering in glucose test strip product. Here, 5 refers to the strongest or highest. |
10.9. | Printed glucose test trip market. |
10.10. | Market forecasts for the use of Ag-based inks in glucose test strips (value and tons) |
10.11. | Printed capacitive sensors used in automotive (infotainment module) and home appliance applications. Source: Polymatech. I took these photos at Nepcon Japan 2017 |
10.12. | Printed capacitive touch sensor unit aimed at first-class seats in passenger airplanes. |
10.13. | Ten-year market forecasts for conductive inks/pasts in printed capacitive touch sensors in $m and tonnes |
11. | 3D ANTENNAS AND CONFORMAL PRINTING ON CURVED SURFACES |
11.1. | Laser Direct Structuring and MID |
11.1. | Many components in a typical consumer electronics device such as a mobile phone are or can potentially be printed. |
11.2. | Schematic showing the sales volume of phones. |
11.2. | Aerosol deposition |
11.3. | Others ways of printing structurally-integrated antennas |
11.3. | The production process using LDS. |
11.4. | A typical smartphone antenna made using LDS. |
11.4. | Market projections for printed 3D antennas |
11.5. | Examples of LDS products on the market. |
11.6. | The aerosol deposition process and its key features. |
11.7. | The core components making up an aerosol deposition machine |
11.8. | Aerosol deposited 3D antennas directly on mobile phone components |
11.9. | Comparing the LDS vs aerosol processes. |
11.10. | (Left) An antenna dispensing machine and (right) an antenna being printed (dispensed) directly on the phone case. |
11.11. | Ten-year market projections for the use of conductive inks (silver nano inks) in printing 3D antennas. |
12. | THERMOFORMED OR IN-MOULD ELECTRONICS |
12.1. | Automotive |
12.1. | The process starts by printing on a flats or 3D substrate before being thermoformed into a 3D shape. |
12.2. | Examples of use case of IME technology in the automotive industry |
12.2. | Definition of terms |
12.2. | In-mould electronics in consumer electronics |
12.3. | Ink requirements in in-mould electronics |
12.3. | Picture of an actual IME overhead console by T-Ink and DuPont |
12.4. | AC control unit for cars using DuPont inks. This is not yet commercial but DuPont confirms that it has two products that are close to qualification. Source: DuPont, photo taken at the Wearable Expo Japan 2017 |
12.4. | Suppliers of IME inks rapidly multiply |
12.5. | Other materials used in in-mould electronics: the merit of a portfolio approach |
12.5. | Comparison of overhead control panels |
12.5.1. | IME PEODT |
12.5.2. | IME Carbon nanotubes |
12.5.3. | IME Metal mesh |
12.5.4. | Insert moulding or transfer attachment will do just fine? |
12.6. | Market forecasts for IME conductive inks |
12.6. | The formation of car overhead consoles using in-mould electronics is a multi-step process. |
12.7. | Application ideas for the use of IME technology in consumer electronics |
12.8. | A commercialized washing machine with an IME switch board |
12.9. | Example of how in-mould electronics (here referred to as structural electronics) can result in the formation of simple and elegant designs. |
12.10. | Schematic showing how TactoTek makes its structural or in-mould electronics. |
12.11. | The inks formulated for IME are expected to withstand elongations as high as 60% without failure although the resistance does typically undergo change (e.g., 30% or so) |
12.12. | These images demonstrate the impact of ink formulation on its performance after being stretched. |
12.13. | Examples of IME inks by DuPont, T-Ink, Henkel, NRCC, Yoyobo, Fujikura Kasei and others |
12.14. | The process for IME using PEDOT films |
12.15. | Examples of IME PEDOT thermoformed films and some product demonstrators. |
12.16. | Air conditioning controller unit for a car. |
12.17. | Increase in resistance as a function of change in length. |
12.18. | Examples of thermoformed products made using a CNT-on-PC film |
12.19. | Examples of SWCNT and DWCNT films thermoformed into 3D shapes |
12.20. | Example of a 3D-shaped IME dome made using Fujifilm's metal mesh technology |
12.21. | Example of an IME 3D car touch screen using copper metal mesh and a thermoformed silver nanoparticle 3D surface |
12.22. | Example of an transferred printed functional film onto a 3D object |
12.23. | Ten-year market projections for conductive inks/pastes in IME automotive applications in $m and tonnes |
12.24. | Ten-year market projections for IME conductive inks in the home appliances in $m and tonnes |
13. | STRETCHABLE INKS FOR ELECTRONIC TEXTILES |
13.1. | Electronic textile industry |
13.1. | The resistivity and loading levels of graphene inks by different graphene suppliers |
13.1. | Medium-term market projections for smart textiles. |
13.2. | Some examples of prominent e-textile products are shown in this slide. |
13.2. | Stretchable inks: general observations |
13.3. | Stretchable e-textile inks multiply |
13.3. | Percentage of e-textile players using each material type |
13.4. | Microcracks and voids appear in a printed conductive lines under stretch causing it to lose its conductivity. |
13.4. | Performance of stretchable conductive inks |
13.5. | Future performance improvements for stretchable inks |
13.5. | Stretchable inks containing only Ag flakes show great resistivity variations under stretch compared to inks containing a distribution of particle sizes. |
13.6. | Printing a typical conductor on a fabric or textile is currently a four-step process |
13.6. | The role of particle size and resin in stretchable inks |
13.7. | The role of pattern design in stretchable conductive inks |
13.7. | Apparatus used for laminating printed conductive films onto textiles |
13.8. | Examples of stretchable e-textile conductive inks from Taiyo, NAmics, Toyobo, Jujo Chemical and Ash Chemical |
13.8. | Washability for stretchable conductive inks |
13.9. | Encapsulant choice for stretchable inks |
13.9. | Examples of stretchable e-textile conductive inks from DuPont, Henkel, Cemedine, Polymatech |
13.10. | Performance characteristics of conductive by Panasonic, Henkel, Fujikura Kasei, DuPont, EMS, Ash Chemical and so on. |
13.10. | The role of the substrate in stretchable inks |
13.11. | Applications of inks in e-textiles |
13.11. | Comparing the performance of GenI and GenII of stretchable inks supplied by the same company to track industry evolutions. |
13.12. | Table qualitatively showing how resin choice affects flexibility, adhesion strenght and heat resistance. Resins considered are acrylic, epoxy, pheno, polyester, urethane, silicone and polymide type |
13.12. | Examples of products with conductive yarns |
13.13. | Graphene as a stretchable e-textile conductive ink |
13.13. | SEM image showing a typical particle size distribution in a stretchable inks |
13.14. | Change in resistance as a function of elongation for the same ink printed in different patterns |
13.14. | PEDOT as a conductive e-textile material |
13.15. | Market projections for stretchable conducive inks |
13.15. | Change of resistance as a function of washing cycles. |
13.16. | TPU alternative being developed by Hitachi Chemical. |
13.17. | TPU alternative being developed by Showa Denko, Osaka Industry, Nikkan Industry, etc |
13.18. | The change in resistance with strain for the same ink printed on the same substrate with and without TPU encapsulation |
13.19. | Effects of straining printed lines on different substrates. The different made by the choice of the substrate is visible with the naked eye as the strain range changes from 0 to 40%. |
13.20. | Examples of wearable products employing conductive inks. |
13.21. | Example of e-textile products and prototypes by Toyobo, Jujo Chemical and DuPont. |
13.22. | Examples of e-textile products using printed conductive inks |
13.23. | Recent examples of e-textile products using printed conductive inks |
13.24. | Recent examples of e-textile products using printed conductive inks |
13.25. | Recent examples of e-textile products using printed conductive inks |
13.26. | Examples of e-textile sports products made using conductive yarns. |
13.27. | Examples of prototype of graphene inks on textile and graphene stretch sensors. |
13.28. | Examples of graphene-including electronic textiles |
13.29. | Examples of PEDOT used as a conductive e-textile materials |
13.30. | Ten-year market projections for stretchable conductive inks in e-textiles in $m and tonnes |
14. | STRETCHABLE CONDUCTIVE INKS IN FLEXIBLE AND/OR STRETCHABLE CIRCUIT BOARDS |
14.1. | Two examples of wearable devices on the right hand side |
14.2. | Stretchable printed circuit board following the rigid island and stretchable connector approach |
14.3. | Example of stretchable interconnects |
14.4. | Example of printed flexible interconnects for cameras in fax machines (left) and stretchable printed interconnects for ECGs |
15. | PRINTED CIRCUIT BOARD MANUFACTURING AND PROTOTYPING |
15.1. | Background to the PCB industry |
15.1. | Left: example of pre-PCV electronics wit rats nest wiring. Right: example of early PCB. |
15.2. | Examples of through-hole (left) and SMD PCB (right). |
15.2. | 'Printing' PCBs for the hobbyist and DIY market |
15.2.1. | Comments |
15.3. | 'Printing' professional multi-layer PCBs |
15.3. | Schematic using a typical construction of a double-layer (left) and multilayer (right) PCB. |
15.4. | Breakdown of the PCB market by the number of layers |
15.4. | Print seed and plate approach |
15.5. | Progress on seed-and-plate PCBs |
15.5. | Traditional PCBs are a mature technology |
15.6. | Production steps involved in manufacturing a multi-layer PCB. |
15.6. | Comparison of different PCB techniques |
15.7. | Market for conductive inks in desktop and professional PCB printing |
15.7. | PCB market by production territory |
15.8. | PCB design files are often sent to the other side of the world to be manufactured and shipped back |
15.9. | CNC machine create double-sided rigid PCB. |
15.10. | AgIC have developed a specially-coated PET substrate for inkjetting |
15.11. | Left: example of a desktop printed single-sided PCB on a plastic (flexible) substrate. Right: example of a Cartesian desktop PCB printer. |
15.12. | Example of a bot factory machine in the IDTechEx office |
15.13. | Professional multi-layer desktop PCB printer by NanoDimension (beta version) |
15.14. | Professional multi-layer desktop PCB printer by NanoDimension (final version on sale) |
15.15. | Example of a multi-layer professional PCB printed using a professional desktop PCB printers. |
15.16. | Example of a lower cost and lower spec multi-layer professional PCB printer |
15.17. | Classification and structure of FPCB |
15.18. | Example of a PCB manufactured using inkjet printed photoresist. Here, printing replaces photolithography |
15.19. | seed-and-plat PCB using screen printing by Tatsutu |
15.20. | prototypes of screen printed seed and plated PCB with L/S 50/59 |
15.21. | Comparison of different PCB techniques |
15.22. | Market for conductive inks in desktop and professional PCB printing by value |
15.23. | Market for conductive inks in desktop and professional PCB printing by tones |
16. | ITO REPLACEMENT (TRANSPARENT CONDUCTING FILMS) |
16.1. | Market forecast for transparent conductive films |
16.1. | Examples of application that use a transparent conductive layer (glass or film) and the performance of ITO films |
16.2. | Ten-year market forecast for transparent conductive films split by TCF technology |
16.2. | Changing market requirements |
16.3. | A brutal consolidation set in but has now ended? |
16.3. | The sheet resistance requirements scale with the display size. |
16.4. | Sheet resistance requirements and efficiency of organic photovoltaic. |
16.4. | Progress and opportunities for conductive inks |
16.4.1. | Embossing followed by silver nanoparticle printing |
16.4.2. | Self-assembled silver nanoparticle films |
16.4.3. | Inkjet printed silver nanoparticles as transparent conducting films |
16.5. | Direct printing of fine line metal mesh |
16.5. | Sheet resistance as a function of radius curvature for ITO films. ITO cracks and its sheet resistance goes up when the film is bent. |
16.6. | Sheet resistance as a function of bending cycle or angle for different TCF technologies such as metal mesh, PEDOT, silver nanowires and carbon nanotubes. |
16.6. | Direct printing can go ultra-fine feature, achieving sub-micron resolution? |
16.7. | Printing of metal mesh TCF using photo-patterned conductive pasts |
16.7. | ITO film price drop from $35/sqm to $18/sqm in a space of two years |
16.8. | Comparing the market forecast for medium-sized (e.g., AIOs) touch screens pre and post 2012. |
16.8. | Direct screen printing of metal mesh films for ultra large area displays |
16.9. | UV patterned silver nanoparticle based metal mesh |
16.9. | Sales of TPK by touch display size. |
16.10. | Quantitatively benchmarking different transparent conductive film technologies |
16.10. | Market Projections |
16.11. | The process flow for making TCFs developed by NanoGrid based in Suzhou |
16.12. | Nanoimprint technology process flow for establishing a metal mesh with 5um linewidths |
16.13. | Printed silver nanoparticle inks and a large touch module |
16.14. | ClearJet inkjet prints drops of specially formulated silver nano inks, which then self-assemble into a pattern shown above to form a conductive network that is also transparent |
16.15. | Process flow for gravure offset printing metal mesh with 5um linewidths |
16.16. | Plastic surfaces covered with printed transparent Ag metal mesh with 5um linewidth |
16.17. | Further examples of directly printed fineline metal mesh films (Shashin Kagaku and Komori) |
16.18. | Direct printing achieving ultrafine features |
16.19. | Mould making process for enabling R2R printing to achieve ultra finefeatures using nanoinks |
16.20. | Printing drum, process and results for printing metal mesh with nanometer scale linewidths |
16.21. | Metal mesh TCF made using screen printed photo-patternable conductive pastes. Here, we see linewidths as low as 3.5um, a prototype touch screen and flexibility data. |
16.22. | 3M large-area touch table made using 3um metal mesh |
16.23. | Large area touch table with screen printed metal mesh |
16.24. | High performance metal mesh using UV patterned silver nanoparticles |
16.25. | Ten-year market projections for the use of silver nano inks as an ITO replacement |
17. | CONDUCTIVE PENS |
17.1. | Conductive pattern drawn using an ink supplier by Electronics Inks. The pen shown in the photo is the conductive ink that Sakura and Electroninks jointly developed. |
17.2. | Examples of applications and performance levels of a conductive ink developed by Dream Inks in China. |
17.3. | Colloidal's ink curing and resistivity |
17.4. | Example of conductive pattern inkjet-printed using an Epson printed and Colloidal's inks. |
18. | MOBILE PHONE DIGITIZERS- HIGH-VOLUME MARKET FOR SILVER OR COPPER NANOPARTICLE INKS? |
18.1. | The structure of a digitizer in a mobile phone. |
18.2. | Value chain of printed digitizers in consumer electronics from powders to devices. |
18.3. | results of a 5.5inch digitizer with printed Cu lines |
19. | OLED LIGHTING MARKET |
19.1. | OLED Lighting market dynamics and challenges |
19.1. | Commercial and prototype OLED vs existing (2013 data) LED performance levels |
19.2. | Examples of LED and OLED lighting installations showing that LED can achieve effective surface emission thanks to the use of waveguides. |
19.2. | OLED lighting in search of a unique |
19.3. | Cost projections of OLED lighting |
19.3. | Flexible, thin and light-weight OLED lighting products launched by LG Chem and Konica Minolta. |
19.4. | Cost projections in $/Klm as a function of year. |
19.4. | OLED lighting market forecast |
19.5. | Requirements from conductive inks in OLED lighting |
19.5. | Examples of latest OLED lighting installations in museums, nightclubs, festivals and libraries. |
19.6. | Ten-year market projections for OLED lighting as a function of year segmented by end application |
19.6. | Market projections |
19.7. | Structure of a typical OLED lighting device |
19.8. | Ten-year market projections for silver nanoinks in OLED lighting applications. |
20. | LARGE AREA LED LIGHTING ARRAYS |
20.1. | Why large-area LED array lighting |
20.1. | Large-area LED arrays developed by FlexBright Oy |
20.2. | Printed interconnects over large areas with mounted (pick and place) LEDs for use in decorative purposes. |
20.2. | Examples of LED array lighting |
20.3. | Role of conductive inks in large-area LED arrays |
20.3. | Front and backside of a printed large-area LED array |
20.4. | Example of a flexible LED sheet |
20.4. | Competitive non-printed approach to making the base for large-area LED arrays |
20.5. | Example of LED lighting array on an etch FPCB. |
21. | PRINTED THIN FILM TRANSISTORS |
21.1. | Comparing traditional and printing methods of manufacturing thin film transistors |
21.2. | Examples of printable semiconducting materials and their mobility levels for printed TFTs |
21.2. | Overall market situation for printed RFID logic |
21.3. | Market for printed backplanes for displays |
21.3. | Unit sales of electrophoretic displays between 2010 and 2014 showing the market downturn |
21.4. | Printed photo or x-ray arrays with printed backplanes |
21.4. | Market for printed backplanes for large-area sensor arrays |
21.5. | Latest progress with solution-processable metal oxides |
21.5. | Pressure and temperature sensor arrays with printed transistors |
21.6. | Publication trends for solution-processed metal oxides |
21.6. | Latest progress with fully printed organic thin film transistor arrays |
21.7. | The need for printed nanoparticle inks and the latest progress |
21.7. | High temperatures are often needed to anneal solution processed metal oxide TFTs |
21.8. | Performance and characteristics of Evonik's solution-processed metal oxide TFT |
21.8. | Market forecasts for silver nanoparticles in fully printed thin film transistors |
21.9. | Picture, application and device structure of fully-printed organic TFT array by JAPERA |
21.10. | Microscopic images of printed interconnects for printed thin film transistors and schematic of the printing process |
21.11. | Ten-year market forecasts for conductive inks/pastes in printed TFT/memory |
22. | PRINTED MEMORIES |
22.1. | Revenue and net income of Thin Film Electronics between 2011 and 2015 |
22.2. | Counterfeiting and consumer engagement printed memory tags |
22.2. | Applications of printed thin film memory |
22.3. | The structure of printed memory and the role of printed conductors |
22.3. | Printed temperature sensor tag with printed memory |
22.4. | Image and schematic of the printed memory devices |
22.4. | Market forecasts for conductive inks in printed memories |
22.5. | Images of an actual device, printed memory role, and the process flow |
23. | EMI SHIELDING USING CONDUCTIVE INKS |
23.1. | Which chips have EMI shielding and what method has been used to deposit them |
23.1. | Background to EMI shielding solutions |
23.1. | Example of conductive-adhesive paste EMI shielding tapes: film structure and an example of use case in flexible printed boards |
23.2. | Premium market for high EMI Shielding using PVD |
23.2. | Current market estimates for EMI shielding solutions |
23.3. | Printing or spraying conductive paste as conformal EMI shielding |
23.3. | Transition from metallic cans/cages to conformal coatings for EMI shielding |
23.4. | Why conformal on-chip EMI shielding? |
23.4. | Sputtering vs spraying for conformal EMI shielding |
23.5. | Nano vs micro inks for EMI shielding |
23.5. | Process flow for conformal coatings, printed or sprayed, on chips |
23.6. | Apparatus for spraying conformal coatings on chips |
23.6. | Sputtering currently dominates but printing is a major medium-term future opportunity |
23.7. | Numbers of suppliers working on or launching conformal on-chip EMI shielding pastes increases |
23.7. | Process flow for spraying coating package-level EMI shielding paste |
23.8. | Overcoming the sinking and agglomeration challenges in the spray tank |
23.8. | The challenge of magnetic shielding at low frequencies |
23.9. | Value proposition for magnetic shielding using printed inks |
23.9. | Comparing the shielding effectiveness of a conventional vs specially formulated conductive paste |
23.10. | Image of chips in iphone7 with EMI shielding. |
23.10. | Market forecasts for conductive inks/pastes in consumer electronics EMI shielding- can it be the next big market outside PV? |
23.11. | Duksan is actively seeing to commercialize its package-level conformal EMI shielding paste |
23.12. | Agfa has demonstrated an inkjet printable on-chip conformal coating |
23.13. | Fujikura Kasie has demonstrated its conformal on-chip EMI shielding paste |
23.14. | Effectiveness of copper as an electric and magnetic shield from 10KHz to 1 Gz |
23.15. | Attenuation of magnetic fields by metallic and ferromagnetic materials at low to high frequency ranges |
23.16. | Effective of conductive ink-based magnetic shields at medium to high frequencies |
23.17. | Market forecasts for conductive inks in EMI shielding coatings in consumer electronics |
23.18. | Market forecasts for Ag nano inks in EMI shielding coatings in consumer electronics |
23.19. | Market forecasts for non-nano inks in EMI shielding coatings in consumer electronics |
24. | HIGH THERMAL CONDUCTIVITY SINTERED DIE ATTACH PASTE |
24.1. | Applications and performance of different high power transistors (Thyristor, IGBT (module & discreet), IPM, GCT, etc) |
24.2. | Electronic devices in vehicles in high temperature environments |
24.2. | Sintered die-attach pastes |
24.3. | Material choices for die attach pastes |
24.3. | Cross-section of a power device showing the die attach, the TIM, the heatsink, etc. |
24.4. | Trend in thermal conductivity going from basic solder and low end Ag-filled epoxy to pressured or nano sintered Ag pastes. |
24.4. | Influence of sintering temperature |
24.5. | Performance of sintered Ag paste |
24.5. | Example of a sintering profile |
24.6. | The electrical resistivity vs sintering temperature for a nano Ag based die attach paste |
24.6. | The rise of nanoparticles |
24.7. | The number of suppliers of nano-based and hybrid pastes multiply |
24.7. | Cross-section of sintered die attach paste |
24.8. | Process of going from wet printed line to drying/necking then cured state |
24.8. | Commercial success has already arrived: biggest market for silver nano? |
24.9. | Market forecasts for nano or hybrid sintered Ag die attach paste in value and tonnes |
24.9. | Performance of conventional Ag based sintered die attach pastes |
24.10. | Comparing the thermal cycle behaviour of sintered Ag die attach paste vs high-T solder |
24.11. | Top image: sintering mechanism using a hybrid (nano plus hybrid) composition. Bottom: sintering process for a nano based system. |
24.12. | The cross section of sintered die attach paste before and after experiencing a 1000 thermal cycles |
24.13. | Sintered low temperature Ag die attach paste (150-170C sintering with no pressure) |
24.14. | Market forecast for nano or hybrid sintered Ag die attach paste in value and tonnes. |
25. | CU PASTES FOR FLEXIBLE PCB MARKET |
26. | OBSERVATIONS, INSIGHTS, ESTIMATES AND FORECASTS FOR CU POWDER IN THE MLCC (MULTI-LAYER CERAMIC CAPACITOR) MARKET |
26.1. | Typical structure of MLLC and typical production process thereof |
26.2. | Material breakdown for MLLC (PME vs BME) |
26.2. | Material usage and price analyses for MLCC |
26.3. | Key powder and paste suppliers in the MLCC electrode business |
27. | METAMATERIALS AND ENGINEERED STRUCTURES USING CONDUCTIVE INKS |
27.1. | Nantennas |
27.1. | Design and performance of frequency-selective surface and reflectarray grating with printed conductive inks |
27.2. | Frequency-Selective Transparent Shielding Patterns |
28. | E-READERS |
28.1. | The use of conductive inks in wearable e-reader devices |
28.1. | Ten-year market forecasts for conductive inks/pastes in flexible e-readers |
28.2. | Market forecasts for conductive inks in e-readers |
29. | OTHER NASCENT APPLICATION IDEAS |
29.1. | Battery Heaters |
29.1. | Printed large-area battery and plant heaters |
29.2. | Plant heaters |
30. | SPECIAL CHAPTER: EXISTING AND EMERGING APPLICATIONS OF SILVER NANOPARTICLE INKS |
30.1. | (left) Optomec aerosol printing heads; (right) antennas printed on 3D-shaped objects using aerosol |
30.1.1. | Conformal printing |
30.2. | Desktop and professional single to multi-layer PCB printing |
30.2. | (right) industrial professional multi-layer PCB printers and (left) examples of flat and curved multi-layered printed PCBs |
30.3. | Replacing the switch and TCF layer with Ag NP in a capacitive touch unit |
30.3. | On-chip conformal EMI shielding |
30.4. | Sintered silver die attach pastes |
30.4. | Effectiveness of on-chip conformal EMI shielding |
30.5. | Sintered die attach paste for power modules using nano silver |
30.5. | Directly printed metal mesh |
30.6. | Hybrid (emboss then fill) metal mesh for ITO replacement |
30.6. | (top) supermooth R2R ultrafine metal mesh printing (bottom) S2S flexo metal mesh printing |
30.7. | Process for metal production using the hybrid approach |
30.7. | Inkjet printed metal mesh TCF |
30.8. | Seed layer for plating Cu films for FCCL |
30.8. | Inkjet printed large-area transparent conductive film with fine features |
30.9. | Silver nanoparticle seed layer for plating Cu films |
30.9. | Replacing solder balls for chip assembly |
30.10. | Print seed and plate in wafer-based Si PV |
30.10. | Replacing solder balls for chip assembly |
30.11. | Inkjet printed metal grids for OLED lighting |
30.11. | Top up conductor layer in thin film PV |
30.12. | Seed layer in PCB |
30.13. | Transistor and memory |
30.14. | OLED lighting |
30.15. | Digitizer |
30.16. | Stretchable and in-mold electronic inks |
31. | COMPANY INTERVIEWS |
31.1. | Agfa-Gevaert N.V. |
31.2. | AgIC |
31.3. | Bando Chemical Industries |
31.4. | BeBop Sensors |
31.5. | BotFactory |
31.6. | Cartesian Co |
31.7. | Cima NanoTech Inc |
31.8. | Clariant Produkte (Deutschland) GmbH |
31.9. | ClearJet Ltd |
31.10. | Colloidal Ink Co., Ltd |
31.11. | Conductive Compounds |
31.12. | Daicel Corporation |
31.13. | DuPont |
31.14. | DuPont Advanced Materials |
31.15. | Electroninks Writeables |
31.16. | Flexbright Oy |
31.17. | Fujikura Kasei Co Ltd |
31.18. | Genes 'Ink |
31.19. | Henkel |
31.20. | Hicel Co Ltd |
31.21. | Inkron |
31.22. | InkTec Co., Ltd |
31.23. | Intrinsiq Materials |
31.24. | Komori Corporation |
31.25. | KunShan Hisense Electronics |
31.26. | Lord Corp |
31.27. | Methode Electronics |
31.28. | Nagase America Corporation |
31.29. | NanoComposix |
31.30. | Nano Dimension |
31.31. | NANOGAP |
31.32. | Novacentrix |
31.33. | O-film Tech Co., Ltd |
31.34. | Optomec |
31.35. | Perpetuus Carbon Technologies Limited |
31.36. | Printechnologics |
31.37. | Promethean Particles |
31.38. | Pulse Electronics |
31.39. | PV Nano Cell |
31.40. | Raymor Industries Inc |
31.41. | Showa Denko |
31.42. | Sun Chemical |
31.43. | Tangio Printed Electronics |
31.44. | The Sixth Element |
31.45. | T-Ink |
31.46. | Toda Kogyo Corp |
31.47. | Tokusen USA Inc. |
31.48. | Ulvac Corporation |
31.49. | UT Dots Inc |
31.50. | Vorbeck Materials |
31.51. | Voxel8 |
31.52. | Xerox Research Centre of Canada (XRCC) |
31.53. | Xymox Technologies |
32. | COMPANY PROFILES |
32.1. | Screen Printable Silver Paste |
32.1. | Advanced Nano Products |
32.1. | Properties of the low-melting-point alloy before and after melting (structure and conductivity) |
32.2. | Electron microscope images of the Napra-developed copper paste (left) and of commercially available resin silver paste (right) |
32.2. | AIST and NAPRA |
32.2. | Other Silver Pastes |
32.3. | Inkjet Printable Inks |
32.3. | Amogreentech |
32.3. | Resistivity of silver and copper pastes (Commercially available copper pastes: A, B, and C; Napra-developed copper paste: D; and commercially available silver paste: E) |
32.4. | Resistivity vs. cure temperature for glass-coated silver nanoparticles |
32.4. | Applied Nanotech Inc. |
32.4. | Applied Nanotech products |
32.5. | Ferro's metal products |
32.5. | Asahi Glass Corporation |
32.5. | The annealing process and equipment used for Hitachi Chemical's inks and pastes |
32.6. | Performance of Hitachi Chemical's inks compared to printed circuit board solutions |
32.6. | Asahi Kasei |
32.6. | Outline of Noritake product list |
32.7. | Silver and carbon pastes offered by Toyobo |
32.7. | Cabot |
32.7. | The Pulse Forge principle |
32.8. | Copper pastes developed by Toyobo |
32.8. | Chang Sung Corporation |
32.8. | Performance of Hitachi Chemical's inks compared to printed circuit board solutions |
32.9. | Cima Nanotech |
32.9. | Flexographic formulation of Vor-Ink from Vorbeck |
32.10. | Packaging Natralock® with Siren™ Technology |
32.10. | Ferro |
32.11. | Giga Solar Materials Corp |
32.12. | Harima |
32.13. | Hitachi Chemical |
32.14. | Kishu Giken Kogyo Co.,Ltd. |
32.15. | Liquid X Printed Metals, Inc. |
32.16. | Indium Corporation |
32.17. | NanoMas Technologies |
32.18. | Noritake |
32.19. | Novacentrix |
32.20. | Novacentrix PulseForge |
32.21. | Samsung (former Cheil Industries) |
32.22. | Taiyo |
32.23. | Toyobo |
32.24. | Vorbeck |
IDTECHEX RESEARCH REPORTS AND CONSULTANCY | |
TABLES | |
FIGURES |
Pages | 538 |
---|---|
Figures | 340 |
Forecasts to | 2028 |