Silicon anode batteries: the Holy Grail?

Silicon anode batteries: the Holy Grail?

Franco Gonzalez
Silicon anode batteries: the Holy Grail?
Elon Musk recently announced the use of silicon by Tesla in its automotive batteries: "This is just sort of a baby step in the direction of using silicon in the anode, but we will be increasing the use". This unusual side comment has nonetheless triggered renewed interested in the topic. IDTechEx Research has been studying the topic for some time, and finds that Si anode batteries will generate more than $4 billion in 2026 - see the report Advanced and Post lithium-ion Batteries: Technologies, Markets, Forecasts 2016-2026 for further information.
Let's focus on what is real
The promise of silicon anodes is that they can improve the capacity of standard graphite anodes 10 times, but be careful this is just the anode and this is just in theory. The real question is how an improvement in the anode capacity is reflected in the overall capacity of the battery.
 
This is because the overall battery capacity is increased only by 35% even if Si anodes reach their maximum potential (i.e. 10x graphitic anodes) and the rest of the system remains unchanged. Now the limiting factor would not be the capacity of the anode but the capacity of the cathode, therefore increase in anode capacity has to be matched by increase in cathode capacity.
Living longer
One critical challenge facing Si anode battery technology is its short lifetime or limited cyclability. This is the case because solid silicon anodes massively expand and contract in each cycle, causing mechanical stresses that eventually crack and pulverise the anode structure.
 
Research has found that using composites of carbon materials with silicon reduces the mechanical stresses on the anode. In addition there is a new avenue of emerging materials and additives that can allow such stresses without destroying the anode.
The best is yet to come
After these, many material companies are jumping on this comment resulting in many old and new companies emerging again. Interestingly some of them used to work in developing silicon materials for photovoltaic technologies, but facing the commoditisation of the PV cells industry they have decided to move to the next industry: batteries.
 
IDTechEx Research has interviewed many such companies, finding out what has been achieved in the area. The result of this research has been published now in our new advanced and post lithium-ion battery technologies report - see www.IDTechEx.com/postlithium for further information. We spoke with Panasonic on the matter and what we can say here is what Frank Sinatra used to sing and Panasonic told us: The best is yet to come...
The report
DTechEx Research builds upon its 15 years' experience in analysing emerging energy storage technologies, 45 electric vehicle segments and the future of electronic devices and in order to provide a comprehensive analysis of the current state of development of these technologies and its market potential.
 
Our report Advanced and Post lithium-ion Batteries: Technologies, Markets, Forecasts 2016-2026 focuses on advanced and post lithium ion battery technologies: silicon anode batteries, solid state batteries, sulphur batteries, lithium air batteries, sodium ion batteries and magnesium batteries.
 
A performance benchmark is presented based in practical results achieved so far from different organisations from start-ups, established companies and research organisations.
 
We analyse challenges and commercial strategies by the companies developing them and provide a 10 year market forecast, 2016-2026. We provide company profiles of the key companies involved in the development and commercialisation of these technologies. Our coverage is global including activities from the US to Asia.