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| 1. | EXECUTIVE SUMMARY AND CONCLUSIONS |
| 1.1. | Purpose of this report |
| 1.2. | Definitions, needs and context |
| 1.3. | Benefits of self-healing and what materials are related |
| 1.4. | Types of healing by material formulation and format |
| 1.5. | Spectrum of self-healing capabilities |
| 1.6. | Primary conclusions: needs |
| 1.7. | Primary conclusions: self-healing solutions |
| 1.8. | 2022 state of progress: new self-healing material commercialisation by application |
| 1.9. | 2032 state of progress: new self-healing material commercialisation by application |
| 1.10. | 2042 state of progress: new self-healing material commercialisation by application |
| 1.11. | "Self-healing material" patent assignees and trends |
| 1.12. | Examples of applications |
| 1.12.1. | Healthcare |
| 1.12.2. | Scratch healing: coatings to Lamborghini bodywork |
| 1.13. | Mechanisms |
| 1.13.1. | Viscous creep and other flow mechanisms for healing |
| 1.13.2. | Three automatic self-healing architectures using embedded artefacts |
| 1.13.3. | Self-healing bacterial bio-concrete - automatic healing using pelleted bacteria |
| 1.14. | Biomimetics is a powerful route to self-healing materials |
| 1.15. | Primary conclusions: applications 2022-2042 |
| 1.16. | Technology readiness 2022 |
| 1.16.1. | Readiness of self-healing materials by application |
| 1.16.2. | Technology readiness of multifunctional polymer composites by application |
| 1.17. | Roadmaps 2022-2042 |
| 1.17.1. | Self-healing commercialisation roadmap 2022-2042 |
| 1.17.2. | Solid state battery commercialisation target launch dates by company |
| 1.17.3. | Metamaterial and 6G Reprogrammable Intelligent Surfaces roadmap 2022-2042 |
| 1.18. | Addressable markets |
| 1.18.1. | Self-healing materials sold as such: concrete, medical, other $ million 2022-2042 |
| 1.18.2. | Solid state battery addressable market size GWh, $ million 2021-2031 |
| 1.18.3. | Paint protection film market $ million 2022-2042 |
| 1.18.4. | Automotive paint protection film & self-healing paint global market million vehicles 2022-2042 |
| 1.18.5. | Global cement market billion tonnes by five regions 2022-2042 |
| 1.18.6. | Global market k tonnes for CFRP 2020-2042 |
| 1.18.7. | Printed and flexible electronics market $ million 2020-2030 |
| 1.18.8. | Barrier layer addressable market $ million |
| 1.18.9. | Electromagnetic metamaterial and metasurface market $ billion 2022-2042 by application segment |
| 1.18.10. | Electromagnetic metamaterial and metasurface market $bn 2022-2042 by application segment |
| 1.18.11. | 6G RIS number, area, price, market value 2030-2041 |
| 2. | INTRODUCTION |
| 2.1. | Needs |
| 2.2. | Self-healing basics |
| 2.3. | Chemical families popularly involved in self-healing polymeric systems development |
| 2.4. | Biomimetics |
| 2.5. | Physical options for self-healing |
| 2.6. | The microcapsule option for textile, other coatings, laminates, bulk materials |
| 2.6.1. | Options and benefits |
| 2.6.2. | Important factors for developing microencapsule-based self-healing materials. |
| 2.6.3. | Microcapsule manufacturing options |
| 2.6.4. | Examples of anti-corrosion capsule materials |
| 2.6.5. | Disadvantages |
| 2.6.6. | Recommended route forward |
| 2.7. | Vascular based self-healing |
| 2.7.1. | Overview |
| 2.8. | Intrinsic property of host material for self-healing |
| 2.8.1. | Overview |
| 2.8.2. | Intrinsic self-healing with ionomers |
| 2.8.3. | Ionomer intrinsic self-healing materials in more detail |
| 2.8.4. | Intrinsic self healing by supramolecular bonding |
| 2.9. | Diels-Alder for intrinsic self-healing composites, rubbers, coatings, adhesives, soft robotics |
| 2.10. | Self-healing epoxy-amine coatings |
| 2.11. | Self-healing research examples in general |
| 2.12. | Importance of nanomaterials |
| 2.13. | Relevance of structural electronics |
| 3. | SELF-HEALING MATERIALS IN COMMERCIAL USE 2022-2042 |
| 3.1. | Overview |
| 3.2. | Paint protection film |
| 3.3. | PVC pipes, tubing etc |
| 3.4. | Self healing from bullets and space debris, fuel cell membranes |
| 3.5. | Self-healing concrete |
| 3.6. | Self-healing PVC cutting mats, tubing etc |
| 4. | SELF-HEALING CONSTRUCTION MATERIALS: CONCRETE, CERAMIC, BITUMEN, ASPHALT, FIBER-REINFORCED POLYMERS |
| 4.1. | Concrete and other cementitious materials |
| 4.1.1. | Overview |
| 4.1.2. | Ultra high performance concrete |
| 4.1.3. | Overcoming deterioration of concrete |
| 4.1.4. | Self-healing bacterial bio-concrete |
| 4.1.5. | Self healing bacteria for concrete and more: Imperial College London |
| 4.1.6. | Fungi creating self-healing concrete |
| 4.1.7. | Appraisal of self-healing concrete options |
| 4.2. | Asphalt for roads and other ground surfaces |
| 4.3. | Self-healing fiber-reinforced polymer construction materials |
| 4.3.1. | Overview |
| 4.3.2. | The types of FRP we need to make self-healing |
| 4.3.3. | Advanced FRP now and soon |
| 4.3.4. | The challenge |
| 4.4. | Fibers that strengthen and emit healant in engineering structures |
| 4.5. | Scratch healing from coatings to Lamborghini bodywork |
| 4.6. | Self-healing ceramics |
| 5. | SELF-HEALING IN HEALTHCARE: BIOMATERIALS AND OTHER APPLICATIONS |
| 5.1. | Overview |
| 5.2. | Major focus of self-healing materials research in healthcare |
| 5.3. | Application examples: cell coculture, interface tissues etc. |
| 5.4. | Self-healing sensors - Self-healing, highly sensitive healthcare sensors enabled by metal-ligand coordination |
| 5.5. | Biocompatible polymeric self-healing hydrogels |
| 5.6. | Mechanisms and promising research routes |
| 5.7. | Super strong hydrogel for soft robotics, bioelectronics, cartilage replacement |
| 5.8. | Wound-healing self-healing hydrogels |
| 5.9. | Replacing human tissue and organs |
| 5.9.1. | Tissue engineering objectives and progress |
| 5.9.2. | Self-healing amphiphilic diblock copolypeptide hydrogel |
| 5.9.3. | Hydrogel cross-linked by acylhydrazone bond and thioldisulfide exchange |
| 5.9.4. | Self-healing polyampholytes hydrogel |
| 5.10. | Self-healing adhesives for tissue engineering |
| 5.10.1. | Overview |
| 5.10.2. | Example of adhesive research for tissue engineering |
| 5.11. | Biocompatibility, anti-bacterial, anti-fouling aspects |
| 5.12. | Electronic skin |
| 5.13. | Bone healing and replacement |
| 5.13.1. | Self-healing implants including bone regeneration |
| 5.13.2. | Self-healing 3D printed bone replacement |
| 5.14. | Drug-delivery and cancer therapy self-healing hydrogel research |
| 5.15. | Injectable self-assembling and self-release hydrogels |
| 5.16. | Example of drug loaded nanoparticle delivery from self-healing hydrogel |
| 5.17. | Self-healing repairing cuts in medical parts |
| 6. | SELF-HEALING ANTICORROSION AND ANTIFOULING SURFACES |
| 6.1. | Anti-corrosion coatings |
| 6.2. | Diphenyl phthalate and VOC issues |
| 6.3. | Chromium discredited |
| 6.4. | Silica gel |
| 6.5. | Self-healing polymer anti-corrosion research |
| 6.6. | Self-healing epoxy coating |
| 6.7. | Retention of corrosion inhibitors |
| 6.8. | Healing of hydrophobicity and tribological properties |
| 6.9. | Anti-fouling film and paint |
| 6.10. | Sea Slug Inspired Smart Marine Antifouling Coating with Reversible Chemical Bonds |
| 6.11. | Silicone-Based Fouling-Release Coatings for Marine Antifouling |
| 7. | SELF-HEALING MATERIALS FOR ELECTRONIC, ELECTRIC, OPTICAL DEVICES, DESALINATION, SOFT ROBOTICS |
| 7.1. | Overview |
| 7.2. | Self-healing materials in electronic and electrical components, desalination, electrolysers |
| 7.3. | Membranes for desalination, water recycling, electronics, batteries, fuel cells, solar architecture |
| 7.3.1. | Materials advances now and soon |
| 7.3.2. | Self-healing fuel cell membranes |
| 7.4. | Wide area electronics and electrics need self-healing |
| 7.5. | Barrier layers for displays and photovoltaics |
| 7.6. | Intrinsic self-healing polymers for advanced lithium-based batteries |
| 7.6.1. | Overview |
| 7.6.2. | Lithium-based batteries: capabilities and need for self-healing |
| 7.6.3. | Many self-healing materials routes being considered |
| 7.6.4. | Researched self-healing polymers for silicon anodes |
| 7.6.5. | Intrinsic self-healing PDMS elastomer |
| 7.6.6. | Other options compared |
| 7.7. | Self-healing electrolytes |
| 7.7.1. | Overview |
| 7.7.2. | Solid state electrolytes |
| 7.7.3. | Examples of self-healing polymers as electrolytes |
| 7.8. | Self-healing transistors |
| 7.8.1. | Overview |
| 7.8.2. | Graphene |
| 7.8.3. | Polymeric transistors and sensors |
| 7.9. | Self-healing sensors |
| 7.10. | Conductive patterns and inks |
| 7.11. | Vast areas of metamaterials will need self-healing: basics and applications |
| 7.12. | Self-healing inks and conductive patterning research |
| 7.13. | Self-healing optical and photonic materials |
| 7.14. | Self-healing actuators and robots |
| 7.15. | Self healing polymer capacitors |
| 8. | SELF-HEALING BULK MATERIALS, ELASTOMERS AND COATINGS: RESEARCH PIPELINE TO COMMERCIAL SUCCESS |
| 8.1. | Damage encountered by bulk polymers |
| 8.2. | Examples |
| 8.3. | Routes to self-healing composite parts |
| 8.4. | Comparison of microcapsule approach, microvascular network and hybrid system |
| 8.5. | Mechanisms for covalent-based intrinsic self-healing materials |
| 8.6. | Simulation of self-healing mechanics of crosslinked polymers |
| 8.7. | Self-healing through rapid polymerisation |
| 8.8. | Intrinsic self-healing of bulk polymers |
| 8.9. | Self-healing through reversible crosslinkers |
| 8.10. | Self-healing under water |
| 8.11. | Self-healing elastomers |
| 8.11.1. | Mechanisms and progress |
| 8.11.2. | Research on fourth generation |
| 9. | SHAPE MEMORY ASSISTED SELF-HEALING SMASH: RESEARCH PIPELINE TO COMMERCIAL SUCCESS |
| 9.1. | Shape memory alloys and polymers |
| 9.2. | Shape memory assisted self-healing SMASH with polymers |
| 9.3. | Research examples and trends |
| 9.4. | Polyolefins are promising |
| 9.5. | Polyurethanes are promising |
| 9.6. | Promising polymer self-healing: Close then heal and fiber SMASH |
| 9.6.1. | Close-then-heal |
| 9.6.2. | Fiber dispersion |
| 9.6.3. | Potential applications |
| 9.6.4. | Appraisal of commercialisation 2022-2042 |
| 10. | MORPHING HOSTS AND SELF-HEALING IMPLICATIONS: RESEARCH PIPELINE TO COMMERCIAL SUCCESS |
| 10.1. | Relevance of morphing materials |
| 10.2. | Applications and challenges |
| 10.3. | Modes of active morphing |
| 10.4. | Piezoelectric Actuator Materials |
| 10.5. | Piezoelectric actuators for morphing composites |
| 10.6. | Ultraviolet stimulation |
| 10.7. | Bend-Twist coupling |
| 10.8. | Electroactive polymer composites |
| 10.9. | Corrugated Morphing Skins |
| 10.10. | Passive Morphing |
| 10.11. | Morphing wings timeline |
| 10.12. | Shape memory alloys as host materials |
| 10.13. | Flexsys - adaptive compliant wing |
| 10.14. | Active morphing airfoil |
| 10.15. | Active winglets |
| 10.16. | Morphing skins |
| Slides | 276 |
|---|---|
| Forecasts to | 2042 |